VULCANIZATION OF RUBBERS BY 1, 3-DIPOLAR ADDITION REACTION

1,3-Dipolar Cycloaddition Reaction of Nitrile Oxides to Isatin Imines

  A<span style="font-size: 10.0pt; font-family: 'Times New Roman','serif'; mso-fareast-font-family: 'Times New Roman'; mso-ansi-language: EN-US; mso-fareast-language: EN-US; mso-bidi-language: AR-...

A competitive Diels-Alder/1, 3-dipolar cycloaddition reaction of1-H-imidazole 3-oxide toward sulfonyl methane. A DFT study on the energetic and regioselectivity

The dual diene/1,3-dipolar character of 1-H-imidazole 3-oxide, HIO 1, allows this compound toparticipate in a competitive Diels-Alder (DA)/1,3-dipolar cycloaddition (13DC) reaction toward C=Sdouble bond of the electro-deficient sulfonyl methane SFM 2. The B3LYP/6-311++G(d,p) calculatedrelative Gibbs free energies indicate that among the studied 13DC and DA reactions, former iscompletely preferr...

Ultrasonic Synthesis, Molecular Structure and Mechanistic Study of 1,3-Dipolar Cycloaddition Reaction of 1-Alkynylpyridinium-3-olate and Acetylene Derivatives.

Regioselectively, ethyl propiolate reacted with 1-(propergyl)-pyridinium-3-olate to give two regioisomers; ethyl 4-oxo-8-(prop-2-ynyl)-8-aza-bicyclo(3.2.1)octa-2,6-diene-6-carboxylate 4, ethyl 2-oxo-8-(prop-2-ynyl)-8-aza-bicyclo(3.2.1)octa-3,6-diene-6-carboxylate 5 as well as ethyl 2,6-dihydro-6-(prop-2-ynyl)furo(2,3-c)pyridine-3-carboxylate 6. The obtained compounds were identified by their sp...

Theory & Practice Of Vulcanization

a competitive diels-alder/1, 3-dipolar cycloaddition reaction of1-h-imidazole 3-oxide toward sulfonyl methane. a dft study on the energetic and regioselectivity

the dual diene/1,3-dipolar character of 1-h-imidazole 3-oxide, hio 1, allows this compound toparticipate in a competitive diels-alder (da)/1,3-dipolar cycloaddition (13dc) reaction toward c=sdouble bond of the electro-deficient sulfonyl methane sfm 2. the b3lyp/6-311++g(d,p) calculatedrelative gibbs free energies indicate that among the studied 13dc and da reactions, former iscompletely preferr...